Kinetics and Spectroscopy of BrNO
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Manufacturer: Storming Media
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Binding: Spiral-bound
EAN: 9781423571070
ISBN: 142357107X
Label: Storming Media
Manufacturer: Storming Media
Number Of Pages: 333
Publication Date: 1997
Publisher: Storming Media
Studio: Storming Media
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Editorial Reviews:
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This is a AIR FORCE INST OF TECH WRIGHT-PATTERSON AFB OH SCHOOL OF ENGINEERING report procured by the Pentagon and made available for public release. It has been reproduced in the best form available to the Pentagon. It is not spiral-bound, but rather assembled with Velobinding in a soft, white linen cover. The Storming Media report number is A822723. The abstract provided by the Pentagon follows: The infrared spectra and photochemistry of nitrosyl bromide, BrNO, are important to characterizing the performance of a recently demonstrated Br((2)P1/2)-NO(v=2--> v=1) transfer laser pumped by photolysis of iodine molecules. This wavelength agile, mid-infrared laser may be a desirable source for remote sensing and infrared countermeasures missions. Nitrosyl bromide also plays a role in the destruction of stratospheric ozone. The kinetics of BrNO formation and destruction were examined using time- resolved photolysis techniques. The equilibrium constant for the dark reaction Br2 + 2NO (reversible reaction) 2BrNO was determined as Ksub eq 168 + or - 23 /atm and the rate constant for the forward reaction as k sub f = 1.40 + or - .18 x 10(exp -38) cm to the 6th power/sq molecule/s at 293K. A novel technique for the fitting of the observed time profiles to the three-body kinetics was developed which utilizes the complete temporal profile to establish the rate coefficients.
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